Common multi-word phrases that nearly rhyme with orpiment:

3 syllables:
for comment,
short ascent,
sought comment,
strong cement,
for comments,
for judgment,
or judgment,
quartz cement,
score comments,
short comment,
for placement,
georgia dept.,
short adult,
thought decent,
sharp ascent,
or command,
or consent,
store command,
torque command,
board agents,
broad judgment,
core product,
for adult,
for product,
forced ascent,
forces must,
forth amidst,
or adult,
or product,
or result,
short descent,
store product,
store result,
strong judgment,
wrong judgement,
wrong judgment,
for payment,
sharp comment,
course comments,
court judgement,
court judgment,
forth judgment,
or agents,
short comments,
source comments,
broad pennant,
broad result,
called adult,
store tenant,
wrong result,
board agent,
cause comment,
frank comment,
not comment,
shall comment,
slag cement,
staff comment,
broad consent,
course placement

4 syllables:
before judgment,
before placement,
among decent,
support adult,
savoir comment,
restore command,
author comment,
because judgment,
default judgement,
default judgment,
export agents,
support agents,
transport agents,
water cement,
before payment,
among buddhist,
divorce judgment,
enforce judgment,
forum about,
moral cement,
moral comment,
mortar cement,
record comments,
report comments,
support judgment,
default result,
arouse comment,
before possessed,
export agent,
support agent,
transport agent,
default command

5 syllables:
maori descent,
priori judgement,
priori judgment

7 syllables:
explanatory comment,
declaratory judgement,
declaratory judgment,
defamatory comments,
explanatory comments

Some other possibilities:

What's up with this "phrase rhymes" section?

This experimental new tab on RhymeZone shows you phrases that might be good matches for your multi-syllable query word. For example, the word poetry produces phrase rhymes like boba tea and swollen knee and hopeful he and moments we. Some of these (like "boba tea") are single conceptual units, while others (like "hopeful he") are sentence fragments. Both kinds of results may be useful when writing slant rhymes that cross line boundaries, which are popular in hip hop lyrics and musical theater. Typically, RhymeZone's phrase rhymes are assonant (share vowel sounds) with the query word, with some degree of consonant match as well.

You'll often find lots of options in this tab, including many junky ones that don't work well. Stay tuned while we find the right formula!

Commonly used words are shown in bold. Rare words are dimmed.
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See orpiment used in context: several books and articles.

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